十分有趣的是该体系对甲基丙烯酸甲酯进行光敏自由基引发聚合的速率和其光解反应速率有很大的不同,本文对此现象进行了讨论。
It is interesting to find that the rate of photo-polymerization of MMA initiated by this system was different from the rate of photolysis. This phenomenon was discussed briefly.
十分有趣的是该体系对甲基丙烯酸甲酯进行光敏自由基引发聚合的速率和其光解反应速率有很大的不同,本文对此现象进行了讨论。
It is interesting to find that the rate of photo-polymerization of MMA initiated by this system was different from the rate of photolysis. This phenomenon was d...
引发剂效率引发剂效率定义为,引发剂最初分解形成自由基,并成功引发聚合反应的分数。
The initiator efficiency fis defined as the fraction of the radicals formed in the primary step of initiator decomposition, which are successful in initiating polymerization.
在氮气保护下,反应不能引发丙烯酰胺聚合,说明在反应中没有自由基产生。
Under the protection of nitrogen the reaction system does not induce polymerization of acrylamide indicating no generation of free radicals.
在氮气保护下,反应不能引发丙烯酰胺聚合,说明在反应中没有自由基产生。
Under the protection of nitrogen, the reaction system does not induce polymerization of acrylamide, indicating the generation of no free radicals.
由聚丙烯腈的红外光谱端基分析证实了MST组分与铈离子反应产生的自由基能引发烯类聚合。
The end group analysis of polyacrylonitrile by IR spectrum confirmed that the free radical produced by the reaction of MST and eerie ion could initiate the polymerization of vinyl monomer.
为研究阴离子聚合引发剂萘锂络合物是否可引发自由基聚合,进行了萘锂络合物引发醋酸乙烯聚合的实验。
To study the radical character of naphthalene lithium, which is a classical anionic initiator, the polymerization of vinyl acetate was initiated by it.
经过动力学分析,蒙脱土参与了自由基聚合的链引发过程。
By kinetic analysis, OMMT participates the radical initiation reaction of the chain.
本文综述了表面引发原子转移自由基聚合合成聚合物刷及其最新进展。
This article reviews the progress of the synthesis of polymer brushes using surface-initiated atom transfer radical polymerization.
对于光引发聚合的原理及硫自由基的稳定性对聚合反应的影响也进行了讨论。
The mechanism of photo-induced polymerization and the effect of the stability of sulfur radical on block copolymerization are also discussed.
紧接着,表面引发甲基丙烯酸聚乙二醇酯(PEGMA)原子转移自由基聚合制备梳型聚合物刷。
The comb copolymer brushes were subsequently prepared via surface-initiated atom transfer radical polymerization of poly (ethylene glycol) methyl ether methacrylate (PEGMA).
实验结果表明用表面引发原子转移自由基聚合在多孔氧化铝膜内部形成分子印迹聚合物纳米管是可行的。
The experimental results prove that atom transfer radical polymerization route works well in the formation of molecularly imprinted polymer nanotubes within porous alumina template.
通过由对氯甲基苯甲酸引发的苯乙烯原子转移自由基聚合(ATRP)合成了分子量可控、分子量分布窄的新型功能聚合物。
A novel type of functional polymer with designed structure, controlled molecular weight and low polydispersities can be prepared via ATRP (Atom Transfer Radical Polymerization).
对DTA-丙烯酰胺(AM)组成的氧化还原体系在碱性介质中引发的丙烯酰胺自由基均聚合反应进行了系统研究。
The kinetic and mechanistic features of DTA initiated aqueous polymerization of acrylamide (AM) have been investigated in an alkaline medium.
本发明涉及一种原子转移自由基聚合引发体系及其在制备高分子化合物的应用。
This invention relates to an atom transfer radical polymerization initiating system and its application in the preparation of polymers.
本发明公开了一种聚丙烯接枝共聚物,由一种原子转移自由基聚合引发剂在温和条件下引发聚合制备。
The polypropylene grafted copolymer is prepared through polymerization under mild condition and initiated with one kind of atom transferring free radical polymerization initiator.
分散体包括在反应活性有机分散介质中在自由基引发剂存在下乙烯基单体的聚合产物。
The dispersion comprises the product of polymerization of a vinyl monomer in the presence of a free radical initiator in a reactive organic dispersion medium.
本发明涉及可聚合组合物,所述组合物包含可自由基聚合的酸性树脂和含有多环芳族组分的光引发剂体系。
The invention features a polymerizable composition that comprises a free-radically polymerizable acidic resin, and a photoinitiator system comprising a polycyclic aromatic component.
光引发自由基聚合;
光引发自由基聚合;
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