第一步反应为自由基加成反应。
通过机理分析和对不同引发条件下的自由基加成反应的比较，认为过氧化物引发自由基加成反应制备六氟丁醇具有工业化前景。
According to the discussion of reaction conditions using different initiations, it was believed that peroxide-initiated free-radical addition reaction was a promising method by mechanism analysis.
关于加成的定向问题，可以一直追溯到自由基化学的起源。
The problem of orientation of addition goes right back to the beginning of freeradical chemistry .
可逆加成-断裂链转移（RAFT）聚合是一种基于可逆链转移的活性自由基聚合技术。
Reversible addition-fragmentation chain transfer (RAFT) polymerization was a novel method of living radical polymerization.
用量子化学从头计算法研究了HCN、HNC分子与H原子和电子加成生成的H_2CN自由基异构体的最低总能量构象和净电荷分布。
Using ab initio method, the minimum energy conformations and netcharge distribution have been studied for H_2CN radical isomers formed by addition ofa H atom (or an electron) to HCN (or HNC) molecule.
用量子化学从头计算法研究了HCN、HNC分子与H原子和电子加成生成的H_2CN自由基异构体的最低总能量构象和净电荷分布。
Using ab initio method, the minimum energy conformations and netcharge distribution have been studied for H_2CN radical isomers formed by addition ofa H atom (or an electron) to HCN (or HNC) molecule.
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