本发明公开一种甲醇羰基化法制备甲酸甲酯的方法及其装置。
This invention discloses methanol carbonylation way preparing methyl formate method and its equipment.
结果表明，该配合物催化甲醇羰基化反应具有较好的活性和选择性。
The results show that such complex has good catalytic activity and selectivity for catalytic methanol carbonylation.
报道了螯合型正方平面羰基铑配合物催化甲醇羰基化反应的机理研究。
The mechanism of methanol carbonylation catalyzed by a chelated square planar carbonyl rhodium complex was studied.
研究表明，在催化甲醇羰基化制乙酸的反应中，该配合物显示出高的活性和选择性。
The experiment results of methanol carbonylation have showed that this catalyst is highly active and selective.
在间歇釜式反应器中，进行一氧化碳与甲醇羰基化合成甲酸甲酯的合成，考察甲醇钠碱性催化体系对反应的影响。
Sodium methoxide used as catalyst for the synthesis of methyl formate by carbonylation of methanol was studied, and effect of three kinds of promoter was investigated.
简述了分别以一氧化碳、二氧化碳与甲醇、二甲醚等进行羰基化反应合成碳酸二甲酯(DMC)的研究进展。
Advances in the carbonylation synthesis of dimethyl carbonate (DMC) from methanol or dimethyl ether with carbon monoxide or carbon dioxide were summarized.
结果表明：丙酮羰基在甲醇溶剂中红外诱导伸缩频率位移最大。
The largest solvent induced frequency shift in the infrared spectrum of acetone is seen in the methanol.
阐述了甲醇低压羰基会成醋酸的反应机理、工艺流程和技术特点，同时介绍了甲醇低压羰基合成醋酸的技术进展。
In this paper, reaction mechanism, process and technical character are described. Meanwhile, technical progress of carbonylation of methanol to acetic acid via low pressure is also introduced.
本装置采用BP技术，利用甲醇低压羰基化法生产醋酸。
The plant using BP Technology produces acetic acid with Low Pressure Methanol Carbonylation Process.
在甲醇低压羰基化制醋酸反应器内，化学反应与流体力学状况非常复杂。
Chemical reaction and hydrodynamic status are very complicated in the reactor of acetic acid through low-pressure methanol carbonylation.
分析了目前甲醇液相羰基化制醋酸的现状，综述了甲醇气相羰基化催化研究进展。
This review analyzes the situation of homogeneous carbonylation of methanol to produce acetic acid. The development of the catalysts for vapor-phase carbonylation of methanol were reviewed also.
对甲醇氧化羰基化合成DMC的过程进行了热力学分析。着重计算了合成反应的平衡常数和平衡转化率。
A thermodynamic analysis of synthesis process of DMC by oxidation carbonylation of methanol was carried out with the emphasis on calculations of equilibrium constants and conversions for the reaction.
甲醇液相氧化羰基化法是人们最早研究的非光气法d MC合成工艺，也是众多DMC合成方法中成本最低、最经济的工业路线。
The oxidative carbonylation of methanol route is one of the earliest phosgene-free synthetic routes of DMC, and it also contains the virtue of low cost which made it more economical.
对甲醇气相氧化羰基化法合成碳酸二甲酯(DMC)产物的分离进行了研究。
Separation methods for products from synthesis of dimethyl-carbonate (DMC) by methanol gaseous oxidative carbonylation were investigated.
羰基镍是导致铜基合成甲醇催化剂中毒的物质。
Iron and nickel carbonyl compounds are poisons to copper-based methanol synthesis catalysts.
羰基镍是铜基合成甲醇催化剂的毒物。
Iron and nickel carbonyls can deactivate the copper-based catalyst for methanol synthesis.
结果表明甲醇水溶剂系统有利于低压合成四羰基钴盐；
The results show that the CH 3OH H 2O solvents system is good for the synthesis of ctalyst under a low pressure.
结果表明甲醇水溶剂系统有利于低压合成四羰基钴盐；
The results show that the CH 3OH H 2O solvents system is good for the synthesis of ctalyst under a low pressure.
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