许多高活性手性催化剂的合成，推动了不对称合成的应用研究。
The synthesis of many high activity chiral metallocene catalysts greatly impels the research of asymmetric synthesis.
本课题所研究的是含有多聚苯刚性分子片段的金鸡纳碱类手性催化剂。
This paper focuses on the synthesis of cinchona alkaloid catalysts which contains rigid polybenzene moieties and their application in asymmetric catalytic reactions.
手性亚砜及其衍生物广泛作为重要手性辅剂、手性配体、手性催化剂、手性药物。
Chiral sulfoxides and their derivatives are extensively used as important chiral intermediates, auxiliaries, chiral ligands, catalysts, and chiral drugs.
手性催化剂的制备是不对称催化合成的关键，其中手性配体的研究是一个重要的研究方向。
The chiral catalysts play the key role in the asymmetric catalytic synthesis, in which the chiral ligands are essential.
该方法具有反应条件温和，操作简便，所用手性催化剂合成简单，且活性高，适于工业化应用。
The reaction condition is bland, operation is simple, synthesis of chiral catalyst is simple, and activity is high, it is adequate for industrial generation.
本文综述了手性双恶唑啉的合成及其金属配合物作为手性催化剂在催化不对称反应中的应用研究进展。
The synthesis and applications in catalytic asymmetric synthesis of C2-symmetric chiral bis (oxazoline) and its metal complexes are reviewed in this article.
手性氨基醇是一类具有很大发展潜力的用于催化不对称合成反应的配体或催化剂。
Chiral amino alcohol is a kind of the ligand or catalyst with great potential for the development of catalytic asymmetric synthesis.
各种新的手性相转移催化剂不断涌现，给这一领域的研究增加了新的活力。
A variety of new chiral phase transfer catalysts have emerged to this area and added the new vitality to it.
其中催化剂-苯甲酸丁烯酯手性加合物的生成是反应产物的手性决定步骤。
The turnover-limiting step for the asymmetric allylic oxidation is the formation of chiral catalyst-allyl perbenzoate complexes.
综述了手性氨基醇作为配体或催化剂在不对称合成中的应用及最新进展。
The applications and recent progresses of chiral amino alcohols as either ligands or catalysts in asymmetric synthesis are reviewed.
通过将手性胺和酸基团同时引入到二氧化硅表面制备得到了一种多相双功能催化剂。
A heterogeneous bifunctional catalyst was synthesized by incorporating chiral amine and acid groups into silica.
本文综述了应用手性高分子试剂和催化剂对潜手性化合物通过不对称氧化、还原、烷基化、加成反应进行不对称合成的进展情况。
This review deals with the recent progress in asymmetric synthesis using chiral polymeric reagents and catalysts for oxidation, reduction, alkylation and addition of prochiral compounds.
综述了手性配体金属络合物催化剂催化1,3 -偶极环加成反应的研究进展。
The research advances of the chiral ligands metal complexes catalysts used in asymmetric 1, 3-dipolar cycloaddition reactions were reviewed in this paper.
产品包括通用试剂、药物合成试剂、手性化合物、催化剂及配体、分析试剂、生物试剂等。
The products include general reagents, drug synthesis reagents, chiral compounds, catalysts & ligands, analytical reagents and biochemical reagents.
手性醇是药物合成的重要手性砌块，利用生物催化剂不对称还原羰基化合物是手性醇制备的重要方法。
Chiral alcohols are important building blocks for drug synthesis. The asymmetric reduction of carbonyl compounds with biocatalysts is an important method for producing chiral alcohols.
手性亚砜及其衍生物广泛作为重要手性中间体和辅剂、手性配体和催化剂、手性药物。
Chiral sulfoxides and their derivatives are extensively used as important chiral intermediates and auxiliaries, chiral ligands and catalysts, and chiral drugs.
不对称催化研究中，手性配体(催化剂)的合成是非常重要的部分。
The synthesis of chiral ligands (or catalysts) is a very important part in the research of asymmetric catalysis.
关于手性配体催化二烷基锌一羰基的不对称加成生成光活性醇的反应，从催化剂、不对称催化机理与自催化过程、手性放大等方面进行了概述，参考文献50篇。
The title reaction is reviewed with 50 references, the catalysts, the mechanism of asymmetric catalysis, the self-catalyzed process and the chiral amplification phenomenon are discussed.
所述手性化合物可用作催化剂，优选可用作不对称转移氢化方法中的催化剂。
The chiral compound can be used as a catalyst, preferably in an asymmetric transfer hydrogenation process.
手性离子液体可以作为手性溶剂，催化剂载体或手性诱导剂，应用于手性合成、手性分离和手性催化等领域。
Chiral ionic liquids are used as chiral solvents, catalyst carrier or chiral inducer in chiral synthesis, chiral separation, chiral catalysis and other fields.
本课题的研究内容是方便、简单地合成手性前体hpba，采用化学拆分法制备手性化合物(R) - HPBA，并进行使用手性相转移催化剂不对称合成(？)
In this paper, we expediently, simply synthesized the racemic HPBA, prepared (r) -hpba which using chemical resolution and were engaged in studying the asymmetric synthesis of (?)
本课题的研究内容是方便、简单地合成手性前体hpba，采用化学拆分法制备手性化合物(R) - HPBA，并进行使用手性相转移催化剂不对称合成(？)
In this paper, we expediently, simply synthesized the racemic HPBA, prepared (r) -hpba which using chemical resolution and were engaged in studying the asymmetric synthesis of (?)
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