针对体系的非理想过程,采用UNIFAC基团贡献法计算液液平衡常数,解决了实验数据不足造成的局限。
As to the non-linear process of the system, we calculate the constant of the Liquid-liquid equilibrium by making use of the UNIFAC Method to solve the problem of the lack of experimental data.
本实验探讨了平衡常数的数值是否会因反应物起始浓度不同而发生变化。
This experiment researched that whether the numerical value of equilibrium constant could be affected because of the differences of the reactant's concentration.
本文首先实验测定了7 - ACA结晶热力学数据和粘度、密度、电离平衡常数等必要的基本物性数据。
First, the crystallization thermodynamic data and other basic physicochemical data of solution, such as viscosity, density of 7-aca solution and dissociation constants, were measured by experiments.
实验结果表明,有效扩散系数随温度升高而增大,吸咐平衡常数则正好相反。
With the increase of temperature the adsorption equilibrium constants decrease while the effective diffusivity increases.
实验结果表明,有效扩散系数随温度升高而增大,吸咐平衡常数则正好相反。
With the increase of temperature the adsorption equilibrium constants decrease while the effective diffusivity increases.
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