外消旋体的动力学拆分反应是制备手性化合物的重要方法之一。
The kinetic resolution of raceme is one of the important ways in the synthesis of chiral compounds.
从螺旋理论看,芳香轮烯和非芳香轮烯都是内消旋体和外消旋体的混合物,故都不呈现旋光性。
In the light of the helix theory, aromatic annulenes and non-aromatic annulcncs are all the mixture of the mesomer and raceme, so they haven't opticity activeity.
外消旋体拆分是获得单一手性化合物的重要途径。
Raceme separation is the main rout for preparation of pure enantiomers.
利用外消旋体进行化学-酶催化动态动力学拆分是制备单一手性化合物的有效手段之一。
The chemoenzymatic dynamic kinetic resolution(DKR) of racemates is one of the efficient ways in the preparation of single chiral compounds.
以有机碱为催化剂 ,通过三唑三甲基丙酮与2 ,4-二氯苯甲醛的反应 ,合成了具有生物活性的外消旋体化合物烯唑醇。
By using alkalamides as the catalyst, diniconazole has been synthesized by the reaction of triazolyl-trimethylacetone and 2,4-dichlorobenzaldehyde.
以有机碱为催化剂 ,通过三唑三甲基丙酮与2 ,4-二氯苯甲醛的反应 ,合成了具有生物活性的外消旋体化合物烯唑醇。
By using alkalamides as the catalyst, diniconazole has been synthesized by the reaction of triazolyl-trimethylacetone and 2,4-dichlorobenzaldehyde.
应用推荐