• 吸电子基团使还原电位,推电子基团使还原电位移。

    Usually, the reduction potential is shifted to more positive by electron-attracting groups and to more negative by electron-repulsing groups.

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  • 烷基电子基团增强原子原子之间化学作用力

    The electron withdrawing group (F) being introduced into the alkyl groups of then-hexyl ZDDP is able to strengthen chemical adsorption between ZDDP and Fe atoms.

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  • 拉曼光谱分析结果证明电子基团存在使苯环上c -H提高

    Raman spectroscopy results showed that: the presence of electron withdrawing groups improved the bond energy of C-H in the benzene ring.

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  • 探讨碱性、溶剂极性、离去基团电子基团试剂亲核性对反应影响

    There are impact factor to be discussed such as solvent polarity, nucleofuge, attract electron group the nunucleophilicity of nucleophilic reagent.

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  • 电子基团增强该类配合物对皮秒激光限幅效果原子效应则起相反作用

    Electron withdrawing groups can enhance the limiting effect for this kind of complexes, but the effect of heavy atom ACTS opposite role.

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  • 另外发现电子基团取代卟啉弛豫过程吸电子基团取代卟啉弛豫过程7

    Moreover, We found that the relaxation time of H2TPP with donating electron group is about 7 times faster than that with withdrawing electron group.

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  • 含有电子基团的二硝基苯类化合物反应活性明显高于含有供电子基的二硝基化合物加氢反应

    The dinitrobenzene with electron-withdrawing group can be hydrogenated much easier than the dinitrobenzene with electron-donating group.

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  • 结果表明偶氮苯衍生物分子具有很好的共轭性,吸电子基团作用下,电荷转移明显,展现示出较强极性

    The results indicated that (1) azobenzene derivatives possess good conjugation. When linked with electron-donor and electron-acceptor, the charge transfer is obvious, thus shows strong polarity.

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  • 研究发现无论对于吸电子取代还是电子的取代基烯基亚活性没有任何影响,而邻甲基苯醌前体化合物中所带有的吸电子基团增加反应活性。

    It was found that both the electro-withdraw and electro-donating substituents have no effect on reaction activity and the electro-withdraw substituents can increase the reaction activity.

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  • 并且核试剂体积效应、溶剂效应亲核性影响,底物上电子基团数目吸电子能力电性的影响,以及亲核取代反应的发生部位受哪些因素影响进行探讨

    At the same time, discuss about the impact factor to nucleophilicity such as the number of attract electron group, ability of attract electron and the nucleophilic substitution reaction part.

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  • 并且核试剂体积效应、溶剂效应亲核性影响,底物上电子基团数目吸电子能力电性的影响,以及亲核取代反应的发生部位受哪些因素影响进行探讨

    At the same time, discuss about the impact factor to nucleophilicity such as the number of attract electron group, ability of attract electron and the nucleophilic substitution reaction part.

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