本论文使用不同类型芳香醛与氨基酸酯的加成反应合成了一系列氨基酸酯亚胺类化合物。
A series of imine esters were synthesised by the addition of amino acid esters to aldehydes.
由(R)-丙叉甘油醛得到的手性亚胺1能与烯酮2在温和条件下迅速反应。
Chiral imine 1 derived from (r) glyceraldehyde acetonide could rapidly react with ketenes 2 which was converted from mixed anhydride or acid chloride under mild conditions.
以醛为底物，通过四丁基三溴化铵(TBATB)氧化原位生成的亚胺转化为氰基化产物。
Nitriles were obtained from aldehydes through oxidation of in situ formed the corresponding aldimines using tetrabutylammonium tribromide (TBATB).
以醛为底物，通过四丁基三溴化铵(TBATB)氧化原位生成的亚胺转化为氰基化产物。
Nitriles were obtained from aldehydes through oxidation of in situ formed the corresponding aldimines using tetrabutylammonium tribromide (TBATB).
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