最后我们选用异二丙胺锂(LDA)为碱,在干冰丙酮浴下,合成了烯醇磷酸酯,并有很高的立体选择性。
At last , we used the base: LDA, dry ice-acetone bath , to synthesize the enol phosphates and gain very high rigio-selectivity.
它们是乙酸、苯甲醛、正葵酸、14-甲基十五烷酸甲酯、丙三醇、苯甲酸、6 ,9-十八碳二烯酸甲酯、角鲨烷、硬脂酸和二十烷基油酸酯。
They were acetic acid, benzaldehyde, n caproic acid, 14 methyl pentadecanoic methyl ester, glycerin, benzoic acid, 6,9 octadecadienoic methyl ester, squalane, stearic acid and oleic eicosyl ester.
以二甘醇、碳酸钠、氯丙烯和二氧化碳为原料合成二甘醇双碳酸烯丙酯。
Diglycol allyl percarbonate is synthesized by diglycol, sodium carbonate, chloropropene and carbon dioxide.
在我们的合成方法中,先从-苯乙醇开始合成了-苯乙基氯,再用丙二酸二乙酯的烯醇盐离子进行亲核取代。
First we synthesized the -phenylethyl chloride from -phenylethyl alcohol. Then it was substituted by enolate anion of diethyl malonate and converted to ester.
优选地,蓖麻酸甲酯通过交叉复分解或同质复分解分别转化成高 烯丙一元醇1-癸烯-4-醇或高烯丙多元醇9-十八烯-7,12-二醇。
Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.
优选地,蓖麻酸甲酯通过交叉复分解或同质复分解分别转化成高 烯丙一元醇1-癸烯-4-醇或高烯丙多元醇9-十八烯-7,12-二醇。
Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.
应用推荐