手性氨基醇是一类具有很大发展潜力的用于催化不对称合成反应的配体或催化剂。
Chiral amino alcohol is a kind of the ligand or catalyst with great potential for the development of catalytic asymmetric synthesis.
综述了手性氨基醇作为配体或催化剂在不对称合成中的应用及最新进展。
The applications and recent progresses of chiral amino alcohols as either ligands or catalysts in asymmetric synthesis are reviewed.
在手性催化反应中，手性配体是不对称诱导的手性源，控制着反应的立体化学过程。
As the chiral source of asymmetric induction, the chiral ligands control the procedure of stereochemistry in reaction.
于是，我们和其合作来深入研究该类配体的不对称催化机制和功能，得到了如下有意义的结果。
Thus we cooperate to study the function and mechanism of this catalyst in the asymmetric borane reduction reaction, and the following results are obtained.
综述了近几年来手性配体与铑的配合物在不对称催化氢化研究的新进展。
The recent progress of the chiral ligands-Rhodium complexes in asymmetric catalytic hydrogenation were reviewed in this paper.
综述了近年来联萘衍生物作为手性配体构成的金属络合物在前手性烯、酮及亚胺的不对称氢化反应中的应用。
In this article, the recent application in recent years of metal complexes composed of binaphthyl derivatives in asymmetric hydrogenation of prochiral alkenes, ketones and imines are reviewed.
同时它也可以作为手性配体应用于不对称合成。
It is also widely used in asymmetric synthesis as chiral auxiliaries.
关于手性配体催化二烷基锌一羰基的不对称加成生成光活性醇的反应，从催化剂、不对称催化机理与自催化过程、手性放大等方面进行了概述，参考文献50篇。
The title reaction is reviewed with 50 references, the catalysts, the mechanism of asymmetric catalysis, the self-catalyzed process and the chiral amplification phenomenon are discussed.
手性催化剂的制备是不对称催化合成的关键，其中手性配体的研究是一个重要的研究方向。
The chiral catalysts play the key role in the asymmetric catalytic synthesis, in which the chiral ligands are essential.
本文综述了手性膦配体及其碳碳双键的不对称催化氢化反应研究和最新进展，并对手性膦配体的设计做了分析和总结。
The paper reviewed the study on the chiral phosphines in asymmetric catalytic hydrogenation and their nearest development. Thedesign of chiral phosphines were also evaluated and summarized.
按配位原子的数目和种类进行分类，综述了近年来含硫的手性配体在有机锌试剂和醛等化合物的不对称加成反应中的最新研究进展。
Recent developments in organozinc reagents on asymmetric addition catalyzed by sulfur-containing chiral ligands are reviewed according to the type and number of the coordinating atoms.
手性氨基-羟基化合物是一类用于催化不对称合成和手性辅助合成的重要配体。
Chiral amino-hydroxy compounds have been proved to be a very efficient class of ligands in a variety of catalytic asymmetric syntheses and chiral auxiliary synthesis catalyzed by metallic ions.
第二部分描述了新的手性环状ON NO -型配体的设计合成、表征和在不对称转移氢化反应中的应用。
The second part of this thesis fouses on designed synthesis, characterization of new chiral cyclic ONNO-type ligand and application in asymmetric hydrogenation.
手性双恶唑啉是在不对称催化中广泛应用的一类重要的配体。
Chiral bisoxazolines have been widely applied ligands to asymmetric catalysis and a series of optically active bisoxazolines with rigid backbones and different chelate sizes were synthesized.
将此类配体应用于各类官能化酮的不对称氢化中，取得了很高的对映选择性和催化效率。
When the ligands were applied to the asymmetric hydrogenation of functionalized ketones, excellent catalytic efficiency and stereoselectivities were obtained.
综述了这类手性配体在不对称催化反应中的应用。
Applications of these planar chiral ligands in asymmetric catalysis are reviewed.
综述了手性1，2二苯基1，2 乙二胺及其衍生物的合成，以及作为手性辅助基和手性配体在不对称合成中的应用。
This review summarizes the synthesis and the application of 1,2-diphenyl- 1,2-diaminoethane and its derivatives as chiral auxiliaries, chiral ligands and chiral reagents in asymmetric synthesis.
联二萘酚作为配体在催化不对称反应方面取得了极大的成功，是有机化学家研究的热点。
The study of optical active R-or S-binaphthol and its derivatives as excellent chiral ligands in asymmetric catalytic reaction has obtained significant progress.
不对称催化研究中，手性配体(催化剂)的合成是非常重要的部分。
The synthesis of chiral ligands (or catalysts) is a very important part in the research of asymmetric catalysis.
系统地总结了不对称催化氢化反应的各类手性双膦配体的特点及性能，对于每类配体的最新研究成果进行了较详细的综述。
The characteristics and performances of various kinds of Chiral Biphosphine Ligands in asymmetric catalytic hydrogenation are systematically reviewed with 78 references.
报道了一系列衍生自9，10-二氢菲-9，10-二醇的新型手性配体设计、合成及在不对称催化反应中的应用。
A series of novel chiral ligands derived from (9,10)-dihydrophenanthrene-9,10-diol were designed , synthesized and applied in some asymmetric catalysis.
报道了一系列衍生自9，10-二氢菲-9，10-二醇的新型手性配体设计、合成及在不对称催化反应中的应用。
A series of novel chiral ligands derived from (9,10)-dihydrophenanthrene-9,10-diol were designed , synthesized and applied in some asymmetric catalysis.
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