不对称合成是当代有机合成的热点,不对称催化方法是获取单一异构手性化合物最具有前景的方法之一。
Asymmetric synthesis is the hot point of organic synthesis in recent years. Asymmetric catalytic method is one of the most prospective methods to obtain pure chiral compounds.
手性金属络合物催化硫醚的不对称氧化是合成手性亚砜最有效的方法。
The most efficient way to generate chiral sulfoxides is asymmetric oxidation of prochiral sulfides Catalyzed by chiral metal complexes.
手性胺化合物广泛存在于自然界中并扮演着重要的角色,亚胺的不对称催化还原反应是制备手性胺化合物的最直接有效的方法。
Chiral amines widely existed and play an important role in the nature. Catalytic asymmetric reduction of imines represents one of the most important methods for preparing chiral amines.
铑催化不对称1,4-共轭加成反应是一种非常有效的碳—碳键形成方法。
In this paper, the recent progress in rhodium-catalyzed asymmetric 1,4-conjugate addition reactions is reviewed.
催化不对称合成是制备光学活性化合物的有效方法,金属有机化合物作为试剂或催化剂在这一领域得到了广泛的应用。
The catalyzed asymmetric synthesis was the effective method to prepare the optics active compounds, the pentamethide obtaines the widespread application as the reagent or the catalyst in this domain.
按反应类型介绍了近几年来催化不对称合成非甾体消炎镇痛药萘普生的各种新方法。
Recent developments in the catalytic asymmetric synthesis of non steroidal antiinflammatory drug naproxen is presented according to reaction types.
手性醇是药物合成的重要手性砌块,利用生物催化剂不对称还原羰基化合物是手性醇制备的重要方法。
Chiral alcohols are important building blocks for drug synthesis. The asymmetric reduction of carbonyl compounds with biocatalysts is an important method for producing chiral alcohols.
所述手性化合物可用作催化剂,优选可用作不对称转移氢化方法中的催化剂。
The chiral compound can be used as a catalyst, preferably in an asymmetric transfer hydrogenation process.
化学方法包括手性辅剂诱导、手性氧化剂氧化、手性拆分和不对称催化等。
The chemical methods include chiral auxiliary's induction, chiral oxidant'soxidation, chiral resolution, and enantioselective catalysis.
综述了近年来不同催化体系的不对称合成呐醇的方法,并总结了不同的催化效率和对映选择性的差异。
New methods for asymmetric synthesis of pinacol are reviewed, the catalytic effects and stereo - selectivity with various catalytic systems are discussed in this paper.
综述了近年来不同催化体系的不对称合成呐醇的方法,并总结了不同的催化效率和对映选择性的差异。
New methods for asymmetric synthesis of pinacol are reviewed, the catalytic effects and stereoselectivity with various catalytic systems are discussed in this paper.
综述了近年来不同催化体系的不对称合成呐醇的方法,并总结了不同的催化效率和对映选择性的差异。
New methods for asymmetric synthesis of pinacol are reviewed, the catalytic effects and stereoselectivity with various catalytic systems are discussed in this paper.
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