用离子交换方法制备了铜交换的分子筛，研究了将二价铜还原为一价铜的方法。
Cupric ion exchanged NaY zeolite was prepared. The method to reduce cupric into cuprous exchanged zeolite was studied.
第一部分为二醋酸碘苯、二价铜离子及联咪唑促进下的1，3-二羰基化合物与亚砜的反应研究。
For the first part, we stressed reactions of sulphoxide with 1,3-dicarbonyl compounds promoted by Cu(OAc)2·H2O, 2,2′-biimidazole and iodobenzene diacetate.
在配合物1中，结构中存在一价铜，并且这个一价铜嵌在所有的二价铜之间，这就阻碍了顺磁离子之间的磁耦合，所以这个配合物呈现出非常弱的反铁磁耦合。
In the structure of 1, CuI ion site between the two CuII ions, which blocks the magnetic coupling of the spin center, so the compound show very weak antiferromagnetic behaviors.
在配合物1中，结构中存在一价铜，并且这个一价铜嵌在所有的二价铜之间，这就阻碍了顺磁离子之间的磁耦合，所以这个配合物呈现出非常弱的反铁磁耦合。
In the structure of 1, CuI ion site between the two CuII ions, which blocks the magnetic coupling of the spin center, so the compound show very weak antiferromagnetic behaviors.
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