"I am not satisfied with the result, especially in the first half, " Zaccheroni said.
CNN: Syria shock Saudi Arabia at Asian Cup; Japan snatch draw
Zaccheroni will hope to get them on track with his first game against Lazio on Sunday.
The result left Zaccheroni's team in sixth place, 14 points behind leaders Inter, who host Cagliari on Sunday.
CNN: Bayern join Leverkusen at the top; Juventus falter again
Coach Alberto Zaccheroni's side triumphed 3-0 on penalties after the game was level at 1-1 after 90 minutes and 2-2 after extra time.
Zaccheroni led AC Milan to the Serie A title in 1999 and has also coached Inter Milan, Lazio and Udinese in the top Italian league.
"Zaccheroni will take over the team immediately and will guide this afternoon's training session in Vinovo before being officially unveiled to the media, " it read.
In Italy, Juventus continued their miserable run with a 1-1 draw at lowly Livorno , the second in a row for new head coach Alberto Zaccheroni.
CNN: Bayern join Leverkusen at the top; Juventus falter again
Thursday's 2-1 Coppa Italia defeat to Italian champions Inter Milan proved the final straw and the club released a statement to confirm his departure and Zaccheroni's arrival.
Japan appointed Italian coach Alberto Zaccheroni after Takeshi Okada stood down in July, having taken the "Blue Samurai" into the second round of football's biggest tournament before losing on penalties to Paraguay.
CNN: Syria shock Saudi Arabia at Asian Cup; Japan snatch draw
Zaccheroni's appointment ends, for now, media speculation that Liverpool manager Rafael Benitez would take charge at Juve, but the short-term nature of his contract until June raises questions about the permanence of his stay.
Zaccheroni led Japan to a historic 1-0 friendly win over South American superpowers Argentina in his first match in charge, but the former Inter, AC Milan and Juventus coach was disappointed by his team's efforts at Doha's Qatar SC Stadium.
CNN: Syria shock Saudi Arabia at Asian Cup; Japan snatch draw
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