On average (depending on the typeofcoal used) 1 kWh produces 1.4 pounds of CO2 which would mean a 25-mile journey using 5 kWh would emit around 7 pounds of CO2 compared to your average vehicles emitting 22 pounds of C02.
One obvious way for firms in the power sector to reduce their emissions is to switch the typeof energy they use, for example from inefficient coal-fired power stations to efficient gas stations.