Barcelona stuff Bayer Leverkusen 7-1 and take the tie 10-2 on aggregate.
He then closed the match out with a simple 7-2 tie-break victory.
Behind the active play of Keita, Syracuse closed the half on a 9-2 run to tie it at 34-all and took control with a 19-2 spurt late in the game.
Federer gained an early break in the opening set but his 22-year-old opponent hit back to tie it at 2-2 and then had chances to move ahead for the first time.
And Spain's Magui Serna of Spain ousted Paola Suarez of Argentina 6-2 2-6 6-2 in her first-round tie.
With the tie level 2-2, Donna Kellogg and Jenny Wallwork were beaten 21-15 10-21 21-15 in the women's doubles by the pre-tournament favourites.
David Ferrer beat Stanislas Wawrinka 6-2 6-4 6-0 to give Spain an unassailable lead in the World Group tie after they had led 2-1 overnight.
BBC: David Ferrer secures Spain Davis Cup quarter-final spot
Arsenal won the last-16 first-leg tie against the Spanish side 2-1 at the Emirates.
It was the Islanders' third one-goal advantage in the game and the one that earned them a 2-2 tie in the highly entertaining series that has featured 5-4 and 6-4 finishes at Nassau Coliseum.
But 30-year-old Llodra took control at the net to claim the next two sets before two straight aces in the fourth-set tie-breaker helped him put France 2-0 up and loosen Spain's two-year grip on the cup.
Meanwhile Hessenthaler says he will not watch Sunday's FA Cup first-round draw after being drawn against former club Dover last year, a tie the Gills lost 2-0.
In Phoenix, he hit a grand slam to break a 2-2 tie and beat Italy.
With the tie level at 2-2 going into the second leg, Barcelona made the perfect start when Pedro headed home after just eight minutes.
Dempsey's goal lifted them from last place in the six-nation group to second, one point behind Honduras, which rallied from two goals down for a 2-2 tie at home against Mexico.
The Croatians reeled off five points in a row after trailing 5-2 in the third set tie-break to move ahead once more, only for the Russians to storm back and take the match to a decider.
Their last tie saw them lose 3-2 to Lithuania in March, with Skupski and Fleming winning their doubles encounter in four sets.
The first leg of the tie ended in a 2-2 draw in Kigali and Club Africain will be hopeful of making it through to the next round.
Benesova will face 16th seed Anastasia Pavlyuchenkova , who beat Kristina Barrois 6-2 6-2 in her second-round tie.
In 2005, Swedish referee Anders Frisk was heavily criticised by then Chelsea boss Jose Mourinho after Drogba was controversially sent off in the first leg of a last-16 Champions League tie against Barcelona, which the Spanish side won 2-1.
Pedro Alvarez broke a 2-all tie with an RBI single in the eighth after Matt Harvey left for a pinch-hitter in the seventh.
Petrova won her first-round tie against compatriot Elena Vesnina, triumphing 4-6 6-2 6-3, while Chinese 13th seed Li Na beat Spain's Beatriz Garcia Vidagany 6-0 6-2 to set up a clash with Slovakia's Dominika Cibulkova.
It turned when Callahan scored short-handed to tie the game at 2 early in the second period.
Gold was banned from Birmingham earlier this season, but was cleared to attend the tie, which West Ham lead 2-1.
In the group's other tie Bayern Munich edged Dynamo Kiev 2-1.
But Safin did not have to stretch himself much to seal the set, Lopez making a string of unforced errors to lose the tie-break 7-1 and fall 2-1 behind in sets.
Solid revenues across virtually all major categories and the addition of the Cars 2 and Green Lantern franchises are encouraging, but Wells Fargo analysts say investors want more clarity on matters like inventory, input costs, pricing and the sustainability of products tied to Cars 2 and other entertainment tie-ins.
Felton sparked a 12-2 run that turned a tie game into an 84-74 Knicks lead.
The Scot then dominated the tie-break, despite an angry outburst at 2-0 when he felt a call of "Allez!"
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