Djokovic has a first-round bye at the first event of the European clay-court season, and is scheduled to begin his campaign against either Florent Serra or fellow Frenchman Stephane Robert.
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The Russian, who had a bye in the first round as did all the top eight seeds, will face compatriot Regina Kulikova in the last 16.
The Thai player, who was given a bye in the first round, celebrated becoming the first Asian ever to reach the world's top ten on Monday, but he could not justify his high seeding against clay-court specialist Sanchez.
The 26-year-old will take to the court on Tuesday for a doubles match, then start his singles campaign the following day after receiving a first-round bye as the top seed in the draw despite slipping to fifth in the world rankings.
This is the first week of the NFL season where teams have a bye (Indianapolis and Pittsburgh have the week off).
The Italian upset world number 17 Nicolas Almagro in the first round but it was soon apparent that the 23-year-old was a little out of his depth against Murray, who had received a bye in the first round.
The victory halted a three-game losing streak for Syracuse (23-6, 11-5 Big East) and gave the Orange the third seed and a double-bye for the Big East tournament as they seek their first NCAA bid since 2008.
The victory snapped a three-game losing streak for Syracuse (23-6, 11-5 Big East) and gave the Orange the third seed and a double-bye for the Big East tournament as they seek their first NCAA bid since 2008.
The 30-year-old Italian, who received a first-round bye, is having her best season after fourth-round finishes at the French and US Opens.
Fourth seed Andy Murray, fresh from his Rogers Cup victory in Toronto on Sunday, received a first-round bye, alongside the other top eight players in the world.
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The world No. 7, last year's runner-up to Amelie Mauresmo, has a first-round bye and will begin her title bid against Iveta Benesova of the Czech Republic or fellow Russian Anastasia Pavlyuchenkova, who meet on Tuesday.
World number two Jelena Jankovic is looking forward to her first match in Cincinnati after being given a bye into the second round.
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Nadal has a first-round bye in Abu Dhabi, then plays the winner of the match between U.S. Open and Olympic champion Andy Murray and ninth-ranked Serbian Janko Tipsarevic.
The American, who defeated Timea Bacsinszky of Switzerland in her opening match on Tuesday after a first-round bye, will next face Maria Kirilenko.
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