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Darren Mackie added a second after 76 minutes before Rangers' Nacho Novo was dismissed for a lunge on Stuart Duff.
BBC: Aberdeen 2-0 Rangers
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Ledley's winner followed a free-kick by Ki Sung-Yueng, but Butcher felt Stuart Duff had been harshly penalised for a challenge on Emilio Izaguirre.
BBC: Joe Ledley heads Celtic's winner
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The hosts made a lively start, with Aluko darting down the right before crossing for Stuart Duff, but the midfielder's shot was easily blocked by former Don Lee Mair.
BBC: Steve MacLean and Zander Diamond celebrate
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Langfield proceeded to palm away a Darcheville drive on the counter-attack, while Stuart Duff drove a shot inches wide for the Dons with both sides displaying a tangible sense of urgency.
BBC: Aberdeen 2-0 Rangers
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Bryson made a goal-line clearance to deny Rooney and the home striker's shot was saved by the legs of Bell following a Stuart Duff cross, but the visitors were taking control of the game with their slick passing.
BBC: Sport - Football - Inverness CT 1-3 Kilmarnock