Sinazongwe district commissioner Oliver Pelete told reporters the Chinese managers were being held in prison until their court appearance.
BBC: Chinese bosses charged over Zambian mine shooting
At least 11 workers were injured in the incident at the Collum coal mine in the southern town of Sinazongwe.
The injured men were treated in hospital at Sinazongwe but two were later transferred to a hospital in the capital, Lusaka, said Reuters.
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