Brive did reduce the deficit on 65 minutes when flanker Vosloo barged over after a spell of pressure but the home side were punished for an error from the kick-off.
Stuart Broad had a series of catchers surrounding the off-side and he forced an error from Prince, who drove loosely but was dropped by a diving Alastair Cook in the gully.
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Suker put Miroslav Blazevic's side ahead, but a defensive error allowed right-back Lilian Thuram to equalise with his first ever goal for France.
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And five minutes later an horrendous error from Jensen gifted the home side a second when he allowed O'Hara's volley to squirm through his grasp.
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Justin Morgan's Hull KR side dug deep and got themselves back into the game when an error by Smith gifted possession 20 metres from the Leeds line.
But it was Tade, who scored the winner when the sides met back in February, who gave his side the lead when he tapped home after Mole capitalised on a Jerel Ifil error.
Madrid twice came from behind to draw level, but goalkeeper Iker Casillas' error in stoppage time gifted Villarreal the victory which leaves Juande Ramos' side eight points behind Barca with just two games left.
Poulsen tried to make amends for his error be slipping a ball through to Ngog but the young striker could only side-foot wide under pressure from ex-Reds left-back Dossena.
The home side stretched their lead just after the restart with an O'Connor penalty but another Ulster error allowed the Ospreys back into the game.
An own goal from Park Chu-Young got Argentina off to the perfect start before Higuain nodded in, and after Martin Demichelis' error allowed Lee Chung-Yong to pull a goal back, Maradona's side got the goals their dominance perhaps deserved.
Juve's 39-year-old third-choice goalkeeper Antonio Chimenti made an error-strewn first start of the season against Siena at the weekend as the Turin side let slip a 3-0 lead to draw 3-3, but he was on hand to tip Zamora's set-piece over the bar.
Bordeaux, fresh from defeat in the French League Cup at the weekend, at least saw Tremoulinas partially atone for his earlier error when he cleared off the line from Makoun late on, meaning Laurent Blanc's side, with the comfort of an away goal, will approach the second leg with a glimmer of hope.
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