The 21-year-old, playing in his seventh first-class match, returned five for 39 as the visitors were bowled out for 142.
BBC: Surrey put icing on cake
The pair dominated the afternoon session, adding 186 in the 36 overs between lunch and tea as White reached his seventh first-class hundred.
BBC: Centurions revive Northants hopes
Chris Hamelin, whose bike chain snapped, was the best island performer when he accumulated a sixth and two seventh places in the Rookie 600 class.
BBC: Jersey's racers toil in Norfolk
The gulf in class in 50-over cricket between New Zealand - rated third in the world - and England (seventh) had been cruelly exposed.
BBC: New Zealand thrash awful England
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