She two-footed and underrotated the second jump in her double axel-triple toe loop combination, and also got a deduction for taking off on the wrong edge of her triple lutz.
Third seed Williams had a free run w hen World No.1 Victoria Azarenka pulled out of their semifinal rather than risk a toe injury ahead of Melbourne, while second-ranked Sharapova also withdrew before the start of the tournament with a collarbone injury.
England midfielder Frank Lampard gave Chelsea hope when he toe-poked in a low cross in the second of five extra minutes at the end, but Pavlyuchenko should then have made it safe for Spurs when he inexplicably missed in a three-on-one situation.