It was the second left-hander Williams has played and she will meet another in the last 32 after unseeded Australian Casey Dellacqua defeated Karolina Sprem 7-6 7-6.
The Mets made some cuts Friday: Non-roster pitcher Scott Rice beat out Robert Carson as the second left-hander in the bullpen to make his first major league roster in his 15th professional season.
Indians right-hander Trevor Bauer was to start the second game against left-hander Vidal Nuno, slated to make his major league start.
Mahmood wasted no time in making an impact with the ball as he forced Devon Smith to play on in the third over of the West Indies second innings, the left-hander now having only managed scores of 24, 13, eight and one on tour.
He had John Simpson lbw for a first-ball duck in his opening over before angling one across Scott Newman to have the left-hander caught low down at second slip.
After Worley walked Ike Davis to leave the bases loaded in the second, the short-sleeved right-hander was removed by manager Ron Gardenhire.
The left-hander walked three straight to start the second inning but permitted only Chris Stewart's sacrifice fly.
It was a timely victory for the left-hander, who crashed out in the second round of his last tournament appearance, in Rotterdam two weeks ago.
Swede Henrik Stenson, Australian left-hander Richard Green and Welshman Garry Houston share second place following 67s.
But all was not so smooth for the right-hander, who was called up Monday for the second game of a doubleheader in Cleveland.
Amin and fellow left-hander Fawad Alam shared an enterprising 141 for the second-wicket, which ended shortly before lunch when Amin pulled a Mark Lawson top-spinner and got a top-edge to mid-wicket.
The second run charged to Hill in the third came when Tigers left-hander Kenny Faulk walked Travis Hafner with the bases loaded.
The burly left-hander clipped his first ball confidently but ambled back for a second, the throw ricocheted off Mahendra Dhoni's pads, dislodged the bails and replays found that West, though in his crease, had no part of bat or body grounded.
Iqbal, 20, struck 17 boundaries in his stand of 128 while fellow left-hander Junaid Siddique notched a career-best 78 and shared a second wicket stand of 146 to defy the home team.
The County Championship player of the year award went to Chris Rogers for the second season in succession after another prolific campaign which saw the Australian left-hander score 1243 runs at an average of 56.50.
Pakistan's highest scorer was Butt with 71 and the stylish left-hander warned the Australian batsmen they would face a tricky time when they commence their second innings.
Malan struck the winning runs in the fourth over after lunch to reach his second hundred of the season - and it also took the 22-year-old left-hander to a healthy 400 Championship runs in five games this season.
But the 40-year-old left-hander could not find the same spark that saw him romp to a 66 in the second round and after starting with a birdie he dropped three shots coming home to miss out on the victory that would have seen him overtake Woods as world number one.
But the talented right-hander would have no time for such antics on this occasion as he top-edged the second delivery of the match, off Boyd Rankin, to wicketkeeper Niall O'Brien.
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