Thomson forced Ricardo into a fine save with a powerful 22-yard drive following a corner.
Brodeur, who was within 7:15 of his 121st career shutout, made the save with his shoulder.
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He made a big pad save with under 5 minutes left in the second to keep the Rangers ahead.
The Ibrox side started the second period positively and Whittaker forced Forster into a save with a stinging drive.
Cox then forced Pernis into a save with a controlled shot from the edge of the box that lacked power.
And Hibs ended the half on top, with Riordan forcing Paul Gallacher into a fine, one-handed save with another free-kick.
Meldrum improved on that save with a great stop from substitute Maman's 30-yard effort which was heading for the top corner.
Joel Hanrahan pitched the ninth for his first save with Boston.
Wallace forced another save with yet another long-range strike and Parkin went down under pressure while chasing the rebound but Preston's penalty appeals were turned down.
Forward Freddie Sears, who deserved a goal for his limitless endeavour on the day, then forced Camp to make another fabulous save with a fierce strike.
As Newcastle laboured Fulham continued to create the more dangerous chances and Papa Bouba Diop's long-distance shot almost surprised Given, who made an unconventional save with his knees.
Defoe might have had a hat-trick but Kiraly did well to save with his feet after the striker had beaten Gary Cahill with a deft piece of skill.
BBC: Defoe has scored six league goals for Spurs this season
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Zenit goalkeeper Vyacheslav Malafeev pulled off a fine save with his feet to block a low Darcheville drive as Rangers showed more adventure at the start of the second half.
Nathan Tyson, recalled in place of Radoslaw Majewski, forced a low save with a crisp long-range strike while the Owls keeper did well to keep out a free-kick from Robert Earnshaw.
Oddo crossed from a similar position soon afterwards and, when the ball was not cleared properly, Fiore forced Maik Taylor into a brilliant save with a powerful shot from 20 yards.
Fletcher could have nabbed it for Hibs in the 74th minute when he broke free and went one-on-one with Zaluska, but was thwarted by a fumbled save with the final ball.
Understandably the finish left Gary Megson's team deflated, but they managed to claw their way back into the game with Rob Jones drawing a good Gilks save with a header from a corner.
Adomah dragged another shot wide when well placed soon after as City looked to build on their lead and David Clarkson forced Sullivan into a fine save with an angled drive just after the hour-mark.
Goalkeeper Paul Robinson, who pulled off a fantastic save with his feet to deny Salomon Kalou in extra-time, said he was delighted to have picked up a winners' medal for the first time in his career.
Substitute Benjani Mwaruwari forced another fine save with seconds remaining, before LuaLua almost capped a fine performance with the winner with the last kick of the game - only for Niemi to save well once again.
However, it was Rangers who continued to be the more threatening and Miller forced John Ruddy into a fine save with a low drive and Lafferty sliced wide when found in the clear 12 yards out.
Jamie O'Hara almost brought Tottenham a late reward, volleying Taarabt's deep cross narrowly wide from the angle, and Dimitar Berbatov forced a neat save with a drive, but it would have been ill-deserved after an uninspired display.
Carlos Edwards had two chances to double Ipswich's lead - flashing a shot wide shortly before half-time and then seeing England Under-21 goalkeeper Loach produce a fine save with his feet to keep out his fierce drive.
Pablo Hernandez came on for Cazorla and was the recipient of a delightful pass by Villa and ought to have done better with his shot, an uncertain effort which McGregor was well placed to save with his feet.
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It was the last clear chance in normal time, and Downing tested Kenny six minutes into extra time as he forced him to save with his feet - the keeper recovering to save well from Tuncay at his near post.
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Impressive teenage midfielder Jay Spearing was involved in their two other best attacking moves of the half, firstly forcing keeper Krul into a low save with a 25-yard shot and then later provided a superb pin-point cross from the right which Lucas headed straight at the United keeper from 10 yards out.
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