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Robredo beat John Isner 6-7 6-3 7-6 after Sanchez saw off American Melanie Oudin 6-4 6-4.
CNN: Clijsters makes winning start to 2010
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The 10th seed will next play Alla Kudryavtseva after the Russian defeated American Melanie Oudin 2-6 7-5 7-5.
CNN: Serena maintains Grand Slam record
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She will be replaced by Vania King, with Melanie Oudin, Liezel Huber and Alexa Glatch competing the team.
BBC: Serena Williams
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Varvara Lepchenko, Madison Keys, Sloane Stephens, Bethanie Mattek-Sands, Vania King and Melanie Oudin all advanced to the second round without losing a set.
WSJ: Heard on the Field
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Zheng Jie beat Melanie Oudin of the United States 6-3, 6-1.
NPR: Ex-No. 1 Jankovic Advances At Rainy French Open
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Ivanovic's sixth-seeded compatriot Jankovic, who last year topped the women's rankings despite never having won a Grand Slam tournament, was upset by American qualifier Melanie Oudin.
CNN: Venus through as women's seeds tumble at SW19
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With a 2-0 lead overnight, world No. 11 Flavia Pennetta's 7-5 6-2 victory over Melanie Oudin in Sunday's opening singles match gave the Italians an unassailable lead.
CNN: Italy beat U.S. to win second Fed Cup title
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Teenage star Melanie Oudin continued her heroics with a second singles victory as she beat Julie Coin 7-6 6-4 to give her side an unassailable 3-0 lead.
CNN: Russia edge Fed Cup thriller against Serbia
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Bethanie Mattek-Sands defeated Alize Cornet 7-6 (9-7) 7-5 for her first singles win in the women's teams tournament, while Melanie Oudin beat debutant Pauline Parmentier 6-4 6-4 in the second rubber.
CNN: Injured Serena to miss Paris tournament
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With both the Williams sisters ruled out through injury, Melanie Oudin opened the tie for the hosts with a 6-3 6-3 win over Alla Kudryavtseva -- who was making her Fed Cup debut.
CNN: Champions Italy secure Fed final place
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Seventh seed Vera Zvonareva defeated ninth seed Alona Bondarenko 6-2 6-1, 13th seed Melanie Oudin beat Christina Mchale 6-4 6-0, and eighth seed Daniela Hantuchova battled past Angelique Kerber 6-7 (6-8) 7-5 6-3.
BBC: Caroline Wozniacki beats Patty Schnyder in Charleston