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He somehow dug it out about eight feet short and holed the clutch putt for a par, while Na saw his mid-range effort for a four at the last finish agonisingly on the edge of the cup.
BBC: Ernie Els completes Arnold Palmer Invitational victory
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Third seed Daniel Hantuchova, of Slovakia, gained a 6-2 6-4 victory over Olga Govortsova, of Belarus, while fourth seed Na Li , of China, overcame Russian Yaroslava Shvedova 4-6 6-2 6-0.
BBC: SPORT | Tennis | Cavaday claims second-round spot
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Petrova won her first-round tie against compatriot Elena Vesnina, triumphing 4-6 6-2 6-3, while Chinese 13th seed Li Na beat Spain's Beatriz Garcia Vidagany 6-0 6-2 to set up a clash with Slovakia's Dominika Cibulkova.
CNN: Serena survives epic in Madrid opener
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Russian No. 2 Sharapova will play 20th-seeded compatriot Maria Kirilenko, while the remaining quarterfinal tie pits China's French Open champion Li Na against German No. 18 Angelique Kerber.
CNN: STORY HIGHLIGHTS
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Fourth seed Agnieszka Radwanska eased past Irina-Camelia Begu, while there were also wins for German fifth seed Angelique Kerber and China's sixth seed Li Na .
CNN: Sharapova to face Venus in crunch clash