Spaniard Martinez Sanchez stands in the way of Jankovic's third title at Foro Italico, after the 26th-ranked Spaniard's serve-and-volley game proved too strong for former world number one Ivanovic - now ranked 58.
Giuseppe Mascara cheekily chipped home his penalty and the result was sealed in the final minute when Martinez out-foxed Lucio before cooly converting home Catania's third goal.