Williams picked up an early warning from referee Terry O'Connor but the opening three rounds remained level, with both boxers looking to work their way in behind the leftjab.
Munroe was troubled in the sixth with Nishioka's right jab, left hook combination finding the target far too often, while the champion also started to work the body of the Leicester fighter.
In the fourth, Walker was caught with a jab then, with just over a minute of the round left, another clubbing hook sent him crashing to the canvas for a second time.