That released Vettel, who had a 10.5-second lead over Button when the Brawn emerged from its pit stop.
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The result means that Button extends his lead over the Brazilian by one point to 15 points with three rounds of the championship to go.
Consequently, Button emerged in the lead after the first pit stops and was able rapidly to extend his advantage while Vettel was held up behind Trulli.
After a 1-2 in Australia with Button and Rubens Barrichello they lead the constuctors' championship ahead of Toyota.
As long as they continue to out-score the Brawns slowly but surely they are eating into Button's 21-point lead.
With Glock passing pole-sitter Trulli off the line for the lead, Hamilton rocketed into third, with Button also slipping ahead of Vettel.
Brawn's Button remains in the world championship lead on 68 points but Vettel and Webber have leap-frogged over Barrichello, who angrily accused his own team of costing him victory after the race.
That ensured Button was able to emerge in the lead after the first pit stop period and thereby extend his advantage sufficiently to win the race.
The McLaren drivers were told to save fuel but soon Button was challenging Hamilton and he took the lead briefly by going around the outside of Turn 12, which becomes the inside of Turn 13, the corner on to the pit straight.
After the first round of stops, Button had been slowly eating into Vettel's lead and took his revenge at the second round of pit stops when he made up a second in time in the pit lane and emerged ahead of the Red Bull on track.
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Button cruised to a comfortable victory - extending his championship lead to 12 points, while Vettel fought off a challenge from Trulli in the closing laps.
Button chased the leading Toyotas hard early on and moved into a lead he never lost when they made their pit stops.
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Button pitted two laps later and returned in third, resuming the lead with 12 laps to go - but the action didn't stop there for the Briton.
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But Button, aided by having a clear run out in front, held on to lead home his team-mate.
"The lead hasn't got that much smaller but it's a different person in second now, " added Button.
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