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French qualifier Paul-Henri Mathieu produced a stunning comeback to claim the Kremlin Cup with victory over Sjeng Schalken.
BBC: Mathieu claims shock win
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Meanwhile, in the men's section, local favorite Marat Safin opened his final Kremlin Cup campaign by ousting defending champion and Shanghai Masters winner Nikolay Davydenko in the first round.
CNN: Kirilenko knocks Radwanska out of Kremlin Cup
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"I have played against Radwanska three times before and I won twice so I can say I actually like to play her -- she's not very aggressive and I always have enough time to hit winners, " Kirilenko told the Kremlin Cup Web site.
CNN: Kirilenko knocks Radwanska out of Kremlin Cup