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Two goals from Dutch striker Klaas-Jan Huntelaar helped secure third spot in the league.
CNN: Dortmund close in on another Bundesliga record
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Schalke, beaten 4-2 by the Spaniards in their home leg, twice led through Raul and Klaas-Jan Huntelaar, but were twice pegged back.
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In other friendly action on Saturday, the Netherlands beat Japan 3-0 in Enschede with Robin van Persie, Wesley Sneijder and Klaas-Jan Huntelaar on target.
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The Premier League and European champions have also been linked with David Silva, Thierry Henry, Klaas-Jan Huntelaar and Roque Santa Cruz, who signed a new four-year contract with Blackburn on Friday.
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Dutch international trio Klaas-Jan Huntelaar, who has been linked with Tottenham Hotspur, Rafael van der Vaart and Wesley Sneijder are all thought to be for sale to offset some of the massive spending.
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