The car of Superintedent Jamil Kakar was sprayed with bullets as he was leaving his home.
BBC: Top Pakistan policeman is shot dead in Quetta
Mr Kakar was on his way to a court hearing at the time of the attack.
Police say that Mr Kakar was killed instantly in Friday's attack and that they are investigating the motives behind it.
However, after the Taleban regime was ousted three years ago, Ms Kakar went back to the police - and was instantly given the same job as before.
BBC: Kandahar's woman detective
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