But the lead only lasted nine minutes as defender Juanfran deflected an Angel di Maria free kick into his own net.
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Striker Jo made it 4-0 in the 82nd minute but substitute Louis Saha was sent off in stoppage time for raising his hand to Athens defender Juanfran and will miss the next match against BATE Borisov.
CNN: Champions Shakhtar stroll to Europa victory
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