Yuvraj Singh (113) and Wasim Jaffer (93) had pressed their claims for Test recalls as the hosts declared on 292-4.
Wasim jaffer (12) was the only one to miss out, edging an outswinger from Robin Martin Jenkins in the 17th over.
Left with just four overs to bat out before the close, Vinayak Mane reached six not out and Wasim Jaffer made a single.
Starting the final day on 10-0 needing just 73 to win the second Test, India were cruising before Tremlett dismissed Wasim Jaffer and Dinesh Karthik.
Thomas got his own back when India began their second innings, however, by having Wasim Jaffer caught behind for his second duck of the game.
Jaffer took a boundary off Ryan Sidebottom, Karthik crashed Anderson to the point fence again and India looked well on the way to a 10-wicket victory.
Jaffer took two more boundaries off Sidebottom to move to 22 before skying an attempted hook against Tremlett to gully, where Kevin Pietersen claimed the catch.
Klusener was the first to go, caught off the bowling of rookie spinner Murali Karthik for 97, followed by Kallis caught by Wasim Jaffer off Anil Kumble for 95.
Fast bowler Dale Steyn tried to shake the Indian batsmen up in a hostile new ball spell and struck Sehwag's partner Wasim Jaffer (25) on the upper arm with a short-pitched delivery.
Newcomer Morkel was introduced as first change by South Africa, but he proved expensive as Jaffer picked off two fours in his second over and Tendulkar found the boundary from two successive deliveries in his next.
He was soon withdrawn by Smith and South Africa succeeded in stifling the scoring before Jaffer, after a spell of five maiden overs, fell to Ntini for 26 with the total on 61 as de Villiers claimed another slip catch.
"It's a holistic approach to jewelry as a work of art, " explained Dr. Amin Jaffer, international director of Asian Art at Christie's and author of "Made for Maharajas, " a book on the objects commissioned by Indian princes during the British Raj.
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