Sangakkara top-edged a pull while Dilshan was trapped lbw first ball by a brilliant inswinger.
Justin Langer was lbw to an inswinger and Marcus Trescothick was the first of four Darren Pattinson victims.
Voges then became Willoughby's fourth victim, adjudged leg before wicket to an inswinger.
And Ed Joyce then lost his off-stump to Calum Thorp's inswinger in the sixth to leave Sussex on 16 for two.
Mitchell Johnson offered no stroke to an inswinger from Zaheer Khan and saw his stumps shattered and Sreesanth bowled Ben Hilfenhaus with a yorker.
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Bangladesh had failed to score in Chittagong when Siddique was trapped in front having been hit on the boot by an Iain O'Brien inswinger.
South African captain Hansie Cronje (12) was bowled by a Srinath inswinger, leaving Boucher and Donald to see through the last few overs before stumps.
Having embarrassed Jerome Taylor with a series of outswingers which the batsman missed, he decided enough was enough and uprooted his off stump with an inswinger.
Brad Haddin was bowled by a lovely Nuwan Kulasekara inswinger and Ricky Ponting top-edged a pull off Thisara Perera to leave the score on 32-2 in the seventh over.
The left-hander whose century took just 79 balls, appeared out of sorts, declining to offer a shot to a Shaun Pollock inswinger that would have clipped his off bail.
He struck first when his brilliant inswinger clean bowled Mark Boucher (45) before Johan Botha (12) had his off stump removed following poorly executed swipe at Abdur Rehman's delivery.
And, two overs later, Smith was back in the pavilion when he was undone by a fine inswinger from left-arm seamer Zaheer as India took firm control of the match.
Peters, who swept Taylor off one knee for a massive six, looked on course to reach three figures before Gidman's inswinger sent his middle-stump flying and Taylor found Afzaal's edge.
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The Bulgarian's corner was only cleared back to him and he fired in another dangerous inswinger that bounced off George McCartney into the path of Vassell, who finished with aplomb from the edge of the six-yard box.
Only 20 balls now remained in the day, but that proved enough time for Siddle to send down a booming inswinger which cleaned up Prior and left a bit of a sour taste in the mouth for England fans.
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