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Relegation-threatened Sporting Gijon went down 2-0 at Getafe while Espanyol came back from two goals down to earn a 2-2 draw against Real Sociedad.
CNN: Sixty for Messi as Barcelona beat 10-man Zaragoza
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Smith also lost Nacho Novo, who moved to Sporting Gijon before the start of the season, and obviously viewed the striking positions as his priority.
BBC: Rangers sign Rapid Vienna's Nikica Jelavic for ?4m
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Villarreal, who finished fourth last season, will be joined in the second tier by Sporting Gijon and Racing Santander, who placed 19th and 20th respectively.
CNN: Football fever: Europe's big leagues serve up late drama
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Earlier on Saturday, fourth-placed Sevilla bounced back from the midweek defeat at struggling Valladolid to crush Sporting Gijon 3-0, who had two players sent off.
CNN: STORY HIGHLIGHTS
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Mali striker Fredi Kanoute opened the scoring in the eight minute after his initial header was blocked, and 13th-placed Gijon lost Mate Bilic to a second yellow card on 32.
CNN: STORY HIGHLIGHTS
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Once cast adrift at the foot of the table, Zaragoza are now level on 25 points with Sporting Gijon and Racing Santander, who both drew 1-1 away from home on Sunday.
CNN: Superb Dortmund hit Cologne for six
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Dutch striker Ruud van Nistelrooy announced his retirement following Malaga's 1-0 over Sporting Gijon, after a career which has seen the prolific former Netherlands striker star at Manchester United and Real Madrid.
CNN: Football fever: Europe's big leagues serve up late drama
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Messi capped the win with a deft chip for his ninth goal of the season overall -- one more than Ibrahimovic -- and Keita headed his third of the night from a corner in the 86th minute as Barca moved three points clear of Real Madrid, who were held 0-0 by Sporting Gijon on Saturday.
CNN: Barcelona return to winning ways with Zaragoza rout