And from the resulting corner, United failed to clear their lines and Maurice Edu headed down for Naismith to fire into the net.
The Wolves midfielder made the most of panic in the box three minutes before the break to fire into an empty net.
It got worse for the Dons four minutes into the second half, when Langfield smothered McDonald's attempt at a cross but let the ball slip from his grasp for the Australian striker to fire into the empty net.
The opening half was largely devoid of inspiration and often resembled a meaningless end-of-season encounter until Richard Chaplow's outswinging corner fell to Jones, who took one touch to control the ball and another to fire high into the net from six yards.
However, Gomis was lurking in the area to fire into the roof of the net and make it 2-0.
However, consistent pressure in the second-half paid its dividends as Taylor rounded his marker to fire into the corner of the net to put Ghana back firmly on a 3-2 lead in the 58th minute.
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Ten minutes later he doubled his tally, following up Lampard's initial shot - well blocked by James - to once again fire a rasping shot high into the net.
United continued to press, but Celtic killed off their challenge when Majstorovic dived low to fire into the near corner of the net from Mulgrew's free-kick to the front post.
After Parise feathered a dump-in toward the L.A. goal, Quick tried to fire the puck around the boards behind his net.
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Chapman struck on the half-hour, neatly controlling the ball on the penalty spot, then swivelling to fire a volley into the corner of the net.
The Bolton Wanderers striker was free at the far post to fire home a corner into the top of the net.
Westwood was only able to parry Jack Colback's low drive, with Fallon on hand to fire the loose ball into the roof of the net.
Then Mustapha Hadji hooked a cross from the bye-line into the area, where Whelan was able to fire a shot into the bottom corner of the net.
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His trickery saw him tease and torment Andy Todd and fire in a stinging low cross which Savage almost diverted into his own net.
It was left to a more experienced head to make Chelsea's progression to the quarter-finals secure, as Deco was given time and space in the box to collect Cole's left-wing cross, control and fire in to the bottom right-hand corner of Al Habsi's net.
Celtic's opener arrived in the 14th minute from the boot of Samaras after the former Man City striker picked up a long ball from Landry N'Guemo and twisted around the Motherwell defence to fire in a superb shot from 12 yards out into the top corner of the net.
But it was left to his strike partner to fire the important third goal, Drogba shooting across Carroll and into the corner of the net after being played through by Gudjohnsen.
Suppose you are like me, and once you fire up your laptop to check your email, you are in danger of spending the whole morning on the Net, doing increasingly useless things.
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