Having started from pole, Stoner slipped back at the start but soon regained the lead and seemed in command of the race when he unexpectedly slid off on the fifth lap.
BBC: Valentino Rossi wins Qatar MotoGP as Stoner crashes out
Capello took the lead at the start of the fourth hour while Minassian's Peugeot No.7 was refuelling, but Minassian overtook the Audi No.2 on the inside in the fifth hour on lap 71 to recapture the top spot.
Honda rider Gibernau led for most of the 25 laps in Barcelona, only for Rossi to pass him on lap 23 to take his fifth win of the season on the Yamaha.
BBC: SPORT | Motorsport | Motorbikes | Rossi snatches win from Gibernau
He only snuck into fifth on the last corner of the last lap of the season.
He should have finished fifth, but he had run an extra lap by mistake and was placed seventh.
Button qualified only fifth in Spain, and a poor first lap put him down to ninth, from where he was not able to use the full performance of the car.
However, Glock's decision not to change to wet tires slowed him down on the final lap, allowing Hamilton to pass and finish fifth -- enough for the championship.
Red Bull's Sebastian Vettel, whose team-mate Mark Webber set the fastest time of the first day of the test, was fifth fastest, just dipping under the Australian's best lap with a 1:21.258.
With Massa winning at Interlagos, the Englishman knew he had to finish fifth to claim the title but he had slipped to sixth with one lap to go.
He was passed by McLaren's Lewis Hamilton on the final lap at Brazil's Interlagos circuit, which promoted Hamilton to fifth, enough for the Englishman to claim the drivers' championship.
The following year, Ryan qualified fifth fastest and was next to Steve Plater on the grid, posting a lap at over 121mph, but the bike was plagued with electrical problems and two blown engines on raceday made it a miserable weekend.
With title rival Felipe Massa winning at Interlagos, Hamilton needed at least a fifth-placed finish to secure the title, but was sixth heading into the final lap.
Nick Heidfeld, who set the fastest lap in final practice, kept up his improved run of form to take fifth for BMW Sauber with team-mate Robert Kubica in eighth.
Home hero Fernando Alonso in his Renault claimed fifth while Brazilian Felipe Massa was sixth in his Ferrari, despite running out of fuel on the final lap and coasting over the line.
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