The third ATV, which takes off on March 9th, is named after Italian space pioneer Edoardo Amaldi.
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He is bidding to emulate his brother Edoardo, who took the Scottish Open two years ago, but is sidelined by injury.
The Swede, along with Miguel-Angel Jimenez and Edoardo and Francesco Molinari, have been left out of the opening day's fourball action.
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Italian brothers Edoardo and Francesco Molinari formed another pair, while world number four Lee Westwood teamed up with USPGA champion Martin Kaymer.
Italy have named Kristopher Burton at fly-half, and he will line up alongside Benetton Treviso team-mate Edoardo Gori, who wins his third cap at scrum-half.
Fabio Semenzato, brought into the squad after usual number nine Edoardo Gori injured a shoulder in last week's loss to Ireland, will now make his debut.
After his promising second-round 67, Edoardo Molinari only managed a 73 to move back to five under - eighth in the 12-man field at Sun City.
The European team also included Lee Westwood, Rory McIlroy, Martin Kaymer, Ian Poulter, Ross Fisher, Francesco Molinari, Edoardo Molinari, Peter Hanson, Luke Donald, Padraig Harrington and Miguel Angel Jimenez.
Francesco had five bogeys and failed to make a birdie, while Edoardo slipped to an 81 that contained a triple bogey eight, a double bogey and two closing bogeys.
But Ryder Cup brothers Francesco and Edoardo Molinari were among those who failed to make it through to the final day at St Andrews, along with Swede Peter Hanson.
The Italian, whose brother Edoardo halved with Fowler in singles play at Celtic Manor in 2010, moved up to 10th place on the European Ryder Cup standings after winning by three shots in Seville.
For Europe, Graeme McDowell and Rory McIlroy played with Luke Donald and Martin Kaymer, Harrington and Peter Hanson went out with Lee Westwood and Ross Fisher with Edoardo Molinari and his brother Francesco taking on Ian Poulter and Miguel Angel Jimenez.
In the pro-am format, Montgomerie is playing with his brother Douglas and Ryder Cup hero Graeme McDowell, while Italian brothers Edoardo and Francesco Molinari play in the same fourball alongside amateur partner Gianfranco Zola, the former West Ham manager and Chelsea striker.
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