The fifth-wicket partnership was worth 67 in 15.3 overs before Steve Harmison found Agarkar's edge, Mark Butcher taking a good diving catch at third man.
Siddique, the 21-year-old left-hander, was eventually removed by Jacques Kallis, playing loosely outside off-stump to edge to wicketkeeper Mark Boucher.
And Hughes, 20, had a nightmare start, slashing at a short Steyn delivery off the fourth ball of the first over and only succeeding in getting a faint under-edge through to Mark Boucher.
In helpful conditions for the bowlers, Chanderpaul arrived at the crease after Lancashire had lost Tom Smith to a catch at the wicket and Paul Horton to another at second slip off Balcombe - and immediately saw Mark Chilton edge behind.
Anderson's day did not begin auspiciously, however, as he dropped a regulation catch at slip to deny fellow England star Andrew Flintoff a fourth wicket when he found the edge of night-watchman Mark Davies's bat.
Kieswetter sliced straight to third man when on seven but survived because Morne Morkel was no-balled for over-stepping and South Africa's frustration was compounded as an edge by Pietersen edge bisected Jacques Kallis and keeper Mark Boucher, leaving the two veterans looking at each other and the ball flying to the boundary.
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The former pupil of Pontarddulais Comprehensive School provided a third catch for wicket-keeper Mark Wallace by finding the edge of Will Rudge's bat for his seventh wicket.
Hoffmann gave Scotland hope when he trapped trapped Mal Loye lbw for 15 before Mark Chilton got a leading edge off Dewald Nel to spoon a catch to Hamilton.
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Following their first corner in the sixth minute the ball broke to the edge of the box to Kilmarnock midfielder Mark Reilly, who steadied himself but blasted the ball harmlessly over the bar.
The left-arm seamer then trapped Jacques du Toit lbw for a duck, leaving Leicestershire in disarray at 85 for five but Nixon, assisted by Tom New, at least managed to edge them nearer the follow-on mark of 159.
Ken Doherty recovered from 2-1 down to edge Nigel Bond 3-2, while Mark Williams was sunk 3-0 by Stuart Bingham in the season's first major tournament.
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Morais worked the ball on to his left foot on the edge of the United box on the hour mark and sent his shot swerving over the bar.
Forster who had the first real shot of the game on the five-minute mark, but his effort from the edge of the area was blocked by a Bradford defender.
Amin and fellow left-hander Fawad Alam shared an enterprising 141 for the second-wicket, which ended shortly before lunch when Amin pulled a Mark Lawson top-spinner and got a top-edge to mid-wicket.
Mark Kerr put the Dons ahead with a great strike from the edge of the box into the top corner in 26 minutes.
Hamilton, who has appeared throughout the weekend to have an edge over his closest rivals, headed the Red Bulls of Sebastian Vettel and Mark Webber.
Dupuis followed by pouncing on a rebound off Mark Eaton's shot from the point to push Pittsburgh's edge to 4-0 and send Nabokov skating slowly to the bench in favor of Poulin.
"If the mark was caused by the quad bike it would appear it was following the edge of the furrow, which could have caused an instability, " he said.
After a clear run into the box he slipped a left-foot shot past Heaton from the edge of the six-yard box for a 2-0 lead and a goal to mark his 100th appearance in league football.
Bolton continued to look dangerous after the break and they levelled when the impressive Mark Davies burst through midfield and slipped the ball to Sturridge, whose shot from the edge of the area slipped under Gomes in a moment the Brazilian goalkeeper will certainly not be replaying to his grandchildren.
Their lack of cutting edge was ruthlessly punished by Argentina, who scored two tries in four minutes around the half-hour mark.
Only in the last 20 minutes did the limited Scots find anything resembling an attacking edge, and it resulted in replacement scrum-half Chris Cusiter's try just after the hour mark.
Langfield could have got an equaliser around the half hour mark after good work by Michael Higdon but the midfielder skied his effort over the bar from the edge of the box.
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