Powell timed 9.95 while Richard Thompson of Trinidad (9.98) and Britain's Dwain Chambers (10.04) also qualified.
CAS's verdict opened the door for 100m sprinter Dwain Chambers to compete at his home Games.
"I respect Dwain as an athlete but he's done bad things in the past, " he told the BBC.
Mo Farah and Dwain Chambers were also selected in the 32-strong squad for the event, which starts on 4 March.
And when they say Dwain Chambers can't compete then he can't compete.
"I don't have any mixed feelings at all, because at the start of the year Dwain and I had a conversation, " said Campbell, 36.
Controversial sprinter Dwain Chambers - who has begun a month's trial with the league's bottom club - was among the spectators at the match.
And all this without the Dwain Chambers circus coming to town.
In his absence, the 32-strong Great Britain and Northern Ireland squad for Paris includes Harry Aikines-Aryeetey, Dwain Chambers and Joel Fearon for the men's 60m sprint.
Devonish , Britain's only representative after the withdrawals of Dwain Chambers and trials winner Toby Sandeman, won his morning heat before finishing third in his second-round run in a time of 20.66.
Dwain Chambers, favourite for the 60m, will go head-to-head with Simeon Williamson and Craig Pickering, while Marilyn Okoro (800m) and Mo Farah (3000m) will also be in action after impressing in Birmingham.
With Dwain Chambers already assured of his place in Qatar after victory at the trials, Harry Aikines-Aryeetey started the day's action at the NIA as favourite to grab the second spot after clocking 6.55 last week in Sheffield.
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"Dwain is competing in Athens three days after the European Cup followed closely by Oslo on 27 June and Glasgow on 29 June, all of which are tough races, " said Mark Brodie, a spokesman for Chambers' management company Stellar.
In his fourth European Championships, Dwain Chambers must hold off the brilliant young Frenchman Christophe Lemaitre if he is to win a gold to replace the one from 2002 that was later stripped from him after his admission of doping.
But he hopes that the 'Linford Christie' affect may be felt and a new generation of hurdlers come through as we now have an era of top-class sprinters with the likes of Dwain Chambers, Mark Lewis-Francis, Christian Malcolm and Darren Campbell.
Lewis-Francis will then compete in the UK indoor trials in Sheffield on 12-13 February as he looks to secure a place in the team for the European indoor championships in Paris in March, where Dwain Chambers will be looking to defend the 60m title he won two years ago in Turin.
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