Chopra is on seven-under-par 135 after firing a bogey-free 65 with Australia's Andrew Dodt and China's Liang Wenchong two shots further back.
CNN: Chopra leading rain-hit tournament
Montgomerie was suddenly one over par and seven adrift of Siem and Australian Andrew Dodt at that stage before dropping from 14th to 47th by taking a shocking 42 to the turn and handing in a 76.
BBC: Gallacher posts course record 63 at Celtic Manor
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