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De Goey was forced to tip a goal-bound cross from Michael Reiziger and the Dutch keeper was relieved to see a header from Kluivert rebound off the bar.
BBC: Chelsea's European dream shattered
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Benito Carbone could have equalised with 10 minutes to go when a similar blunder by De Goey left the Blues' goal totally exposed, but he scuffed the shot and it was cleared off the line by Leboeuf.
BBC: Chelsea claim FA Cup glory
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Ex-Newcastle striker Jon Dahl Tomasson has been in great form and Chelsea goalkeeper Ed De Goey's former understudy, Jerzy Dudek has been named as the most in-form keeper in the world on a Fifa list.
BBC: Chelsea look for Dutch courage
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Substitute Dani had two glorious chances to level for Barcelona - but he headed wide after Figo's free-kick had found him unmarked at the far post and then saw another header turned around the post by de Goey.
BBC: Chelsea's European dream shattered