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In an otherwise untidy Scottish display in the field, Kyle Coetzer's stunning one-handed effort at long-on in the final over to remove Mark Boucher was an early contender for catch of the tournament.
BBC: S Africa send Scots crashing out
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The two batsman had already put on 87 coming into the third day and added a further 42 before Boucher played on, bottom-edging an attempted pull off Dwayne Bravo.
BBC: CHOOSE A SPORT
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The Durham paceman has enjoyed a fairytale two days since returning to the Test scene and, although he was dropped by Boucher on 19, he combined canny stroke-making with dogged defence.
BBC: Pietersen ton puts England ahead
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Earlier, Mark Boucher played brightly to make 95 from 119 balls before South Africa declared on 423-7.
BBC: England on course for heavy defeat in Johannesburg Test