Smith and fellow opener Alvaro Petersen (67) put on 153, with Smith overtaking Allan Border to become the top-scoring Test captain before falling for 100.
In the late 1990s the pair cofounded Shree Renuka Sugars in Belgaum, a trading hub near the border of Karnataka and Maharashtra, the country's top sugarcane-producing states.
The last Latin American on the list is Venezuela Army General Jose Eliecer Pinto Gutierrez, top commander in Amazonas state, overseeing security on the Venezuela-Colombia border.