Viduka had a chance to make the game safe in the 72nd minute but he shot over the bar in the box from Ray Parlour's cross from the right.
BBC: SPORT | Football | Premiership | West Brom 1-2 Middlesbrough
United carved open the Hearts defence three minutes before the break, when Daly powered forward and teed up Craig Conway, but the sought-after midfielder blazed a shot over the bar from inside the box.
And goalkeeper Jung Sung-ryong was forced into his first genuine save of the match when he parried Theofanis Gekas's stinging shot on the turn from the edge of the box over the bar for a corner in the 81st minute.
It never looked like being Boro's day from the moment Brazilian striker Afonso Alves crashed a drive from the edge of the box against the bar in the first half as a string of chances failed to produce the elusive goal.
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Killie rode out the initial storm and James Fowler shot over the Hearts bar from the edge of the box when he should have done better.
Tanzania responded strongly just before the break but Mrisho Ngassa missed a glorious opportunity when he fired over the bar from the edge of the box.
Langfield could have got an equaliser around the half hour mark after good work by Michael Higdon but the midfielder skied his effort over the bar from the edge of the box.
The lead took the sting out of the game and Cardiff tried to get themselves back into it with Ross McCormack, back for his first start in almost three months for suspended top-scorer Michael Chopra, lifting the ball over the bar from the edge of the box.
His first touch won him space in the box but he fired over the bar.
Moments later, a low drive from Jim Goodwin was easily gathered by Saints keeper Graeme Smith, then Collin Samuel fired over the Accies bar from just outside the six-yard box at the other end.
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And Brabec went even closer, heading against the bar from six yards after rising unmarked in the box.
The Liverpool keeper was then called into action once more, tipping Vaughan's effort over the bar after the wily midfielder created space in the box.
Substitute Roque Santa Cruz blasted an effort over the bar after finding space on the edge of the box, but Howard was seldom called into making a save.
The 2002 World Cup quarter-finalists also missed a penalty in the second half with Pape Bouba Diop blasting his spot kick against the bar after Ibrahima Faye was brought down in the box.
But the visitors really should have been level before the hour when Blackman's cross found Danny Kedwell, only for the Dons' top-scorer to side foot over the bar from the angle of the six-yard box.
Heath Pearce's attempt off Juninho's free kick was deflected by Perkins to the top of the box, where Luyindula chipped it over the bar in the 38th minute.
However, Killie's Donovan Simmonds almost made the breakthrough in the 27th minute when he controlled Allan Russell's knock-down on the edge of the box, turned and volleyed inches over the bar.
First Anelka curled a shot wide from just outside the box, then Lampard planted a header over the bar from Bosingwa's cross.
Valencia's David Villa hit the bar and Nicola Zigic appeared to be pulled down in the box, but Atletico prevailed and will face Liverpool in the last four.
The visitors were further buoyed when Villanueva went closest to breaking the deadlock when he collected the ball on the edge of the box and his left-footed shot clipped the bar with Jussi Jaaskelainen well beaten.
Despite Young dancing his way through the box and blazing over keeper Sullivan - and the bar - in the opening exchanges, Doncaster more than matched their Premier League counterparts for large portions of the match.
From another corner the former Portsmouth player then blazed a shot over the bar when he mis-controlled a good chance in the penalty box.
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And there was almost a fairytale finish for Anelka as he latched onto a loose ball in the box, but his shot smacked the underside of the bar and bounced away to safety.
After a scramble in the visitors' box, Johnson turned and blasted a shot narrowly over the bar.
Anderson then cracked a drive against the bar, Rooney failed to properly connect with a shot from inside the box and Berbatov slammed an effort into the side netting.
However, they would and should have been behind in the 25th minute when Clinton Morrison got into a great position in the box, but somehow managed to knee the ball over the bar from a yard out.
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