United scored a late winner when Goodwillie chased down Swanson's long pass and steered the ball under Brown and into the net.
Hampshire made a terrible start to their innings when Michael Carberry fell third ball to Chapple, before Brown and John Crawley put on 48 for the second wicket.
James Ormond was named Man of the Match after his four-wicket burst with the new ball, and Ian Ward and Alistair Brown then saw Surrey to the brink of victory with an opening stand of 100.
And Sussex nerves were starting to fray when Rory Hamilton-Brown drove the first ball after tea to point and Luke Wright was taken low down at slip driving hard outside off-stump at Plunkett.
Brady sent a free-kick to the edge of the penalty area, where McGregor headed the ball behind the Hibs defence and Dargo stole in to slot the ball wide of the exposed Brown.
Moments later, Celtic striker Scott McDonald found space on the left and cut the ball back for Scott Brown, whose left-foot shot hit the post on its way out.
That miss was to be severely punished as Juventus wrapped the game up with 13 minutes remaining when Matri released Marchisio, who turned Scott Brown and slotted the ball home.
Beckford, who is a target for a number of leading clubs, took advantage of defensive indecision to latch on to a long ball from Jonny Howson and hold off Wes Brown before beating Tomasz Kuszczak from an acute angle.
However, the striker hurried his shot on the turn from eight yards and hit the ball straight at goalkeeper Mark Brown.
Ronaldo gathered up the loose ball and looked to be clearly fouled by Michael Brown, but referee Mike Riley waved play on.
Then a Paul Diamond effort broke to the unmarked substitute Conan Brown and he blasted the ball past keeper O'Kane for 1-07 to 0-06.
The previously ineffectual McLean raced onto a Steven Thompson header and calmly slotted the ball past goalkeeper Jason Brown for his third goal of the season.
Sreesanth ended the partnership with a double strike just after lunch, Voges edging to Bell at gully and Ali Brown fending a rising ball to Rikki Clarke in the slips.
St Johnstone were more enterprising at the start of the second half and Samuel should have scored when he latched on to Cleveland Taylor's cross but the striker elected to stretch out a foot instead of heading the ball and the effort was collected comfortably by keeper Brown.
The former England opener had scored 37 of Somerset's 45 runs, but then pushed forward to a ball from Andre Adams and snicked a low catch to Alistair Brown at first slip.
Brown's control and strength on the ball generated chances for Austin Friel but the midfielder struggled to make Plummer work.
Earlier, Mike Smith trapped opener Ali Brown lbw with the fourth ball of the day and then saw Mark Ramprakash nick one to Spearman at first slip for 11.
They were almost caught napping early on when Barry Bannan slid a ball inside right-back Wes Brown to find Stewart Downing and it needed centre-back Rio Ferdinand to come across and clear out the danger.
People talk about team formations, 4-4-2 or 5-3-2, but against Brazil Craig Brown will want to get 11 players behind the ball and defend.
"You have to have the ball bounce your way at times and that happened for us, " added Brown.
The striker seemed certain to convert Wes Brown's low, powerful cross but the ball struck Kirkland and slowly dribbled goalwards.
However, Hibs were back on level terms within five minutes of the hosts' opener when Stokes ran onto a Colin Nish ball down the right and drilled home a low effort into the bottom corner of Brown's net.
Dawson fell five overs later to a ball that climbed from Paul Franks, edging to Ali Brown at first slip, but McKenzie and Chris Benham pushed the run-rate up with a partnership of 75 in 19 overs.
The home side offered greater resistance when they came out to bat for a second time, with Michael Carberry and Brown sharing a stand of 63 before Brown, on 30, hooked a ball from Chris Jordan to Matt Nicholson at long-leg.
BBC: SPORT | Cricket | Counties | Surrey spin pair unsettle Hants
Hampshire's response began in the worst possible fashion as openers Michael Brown and Michael Carberry returned to the pavilion without score as Mahmood caused havoc with the ball.
Among them were Russ Abbot, Roy "Chubby" Brown, Eddie Large, Freddie Davies, Tom O'Connor, Tommy Cannon, Bobby Ball and Roy Hudd.
Shunsuke Nakamura, Scott Brown and Paul Hartley or Barry Robson need to keep possession whilst looking to play that incisive ball into the box.
However, when he had reached 58, and with the score on 78-1 in the 22nd over, he smashed the ball straight to Michael Brown at cover.
However, Brown was well positioned in the middle of his goal and was able to stretch and knock the ball over the crossbar.
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