Barry headed in powerfully from six yards out after an excellent run and cross from Ashley Young.
As a forward against France, Ashley Young completed a grand total of seven passes in 94 minutes.
He made eight changes to the team, with Ashley Young, Stewart Downing and Marc Albrighton named as substitutes.
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But the Russian was denied by Ashley Young's midriff as the winger stood firm on the near post.
John Carew pulled Villa level eight minutes later, neatly volleying home at the far post from Ashley Young's cross.
The hosts took an early lead when Ashley Young freed marauding full-back Luke Young for a fine left-foot finish.
One 40-yard crossfield pass from Terry set Ashley Young free down the right.
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Ashley Young met Nathan Delfouneso's cross to make it 2-1 and quickly added a third goal after Heskey's solo run.
We don't have the biggest squad in the world, and currently John Carew is out and Ashley Young is suspended.
Ashley Young's free-kick was headed down by Martin Laursen and Moore was on hand to finish clincally from six yards.
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Suddenly, Stoke were on the back foot and Gareth Barry was inches away from making contact with Ashley Young's cross.
But I almost went for Aston Villa's Ashley Young in the end because he has had an outstanding few months.
Watford's Ashley Young is also expected to sign following his medical after the two clubs agreed a fee at the weekend.
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James Collins and Gabriel Agbonlahor each struck the United woodwork before Villa went ahead when Ashley Young scored from the penalty spot.
Ashley Young twice won first-half penalties and although his first effort was saved, James Milner levelled the aggregate scores with the second.
Villa's wing duo of James Milner and Ashley Young were largely peripheral figures, while in contrast Burnley's wide men were heavily involved.
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Ashley Young wriggled inside from the left flank but his shot deflected wide and the winger also tested Robert Green from 20 yards.
The visitors grew in confidence and began the second half in blistering fashion with Bent and Ashley Young once again the main threats.
Newcastle, despite the increasing desperation of their situation, were offering nothing and Ashley Young fired just over the top after a powerful run.
After Gabriel Agbonlahor hit an early chance straight at Edwin van der Sar, Ashley Young's tackle prevented Ji-Sung Park from giving United the lead.
Volleys from Martin Olsson and Brett Emerton gave Rovers hope before Ashley Young curled home to wrap up the win for Martin O'Neill's side.
"In the full-back areas, especially the left side, James Milner was tearing them to shreds - likewise Ashley Young on the other flank, " he said.
Ashley Young curling's free-kick was superbly tipped away by Green and Villa's top scorer Bent also curled an 18-yard strike just wide via a deflection.
Carew played the ball into Ashley Young who cutely back-heeled a return-pass into the Norwegian's path and he fired across Sorensen to bring Villa level.
Gabriel Agbonlahor scored the winner, heading in from Ashley Young's cross.
The pace of Ashley Young and power and knowhow of Emile Heskey were now proving every bit as threatening as Keane's guile and Cole's direct running.
With the game stretched, Villa surged forward and Ashley Young's cross needed only a touch to produce a goal but Carew and Albrighton were both inches away.
But England hit back when an Ashley Young corner was cleared straight to Walcott, whose 20-yard strike deceived Isaksson and flew into the middle of the net.
The visitors were immediately on the back foot when Shaun Derry was shown a straight red card for a challenge on Ashley Young in conceding a penalty.
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