U.S. Secretary of State Condoleezza Rice is scheduled to arrive at the U.N. first thing the morning.

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Mid-afternoon, and main stage security have built themselves into a reinforced semi-circle as if preparing for war as Australian drum 'n' bass metalers Pendulum arrive - it's officially their 150th show.

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And counselors who are now starting to arrive, especially from a U.N. organization, UNICEF, are hoping to be finally be able to at least identify some of the worst cases and give them some help.

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The U.N. refugee agency says more than 500 arrive every day.

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The U.N. and other agencies are providing aid, but as more people arrive every day, the conditions become more difficult, Duplat said.

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After days of trying to obtain permission from Syrian authorities to travel to the country, Valerie Amos, U.N. under-secretary-general for humanitarian affairs and emergency relief coordinator, will arrive Wednesday in Damascus, she said.

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