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Poland's Agnieszka Radwanska eased into the quarterfinals when she beat Hungary's Greta Arn of Hungary 6-3, 6-4.
CNN: Nadal wins in Barcelona, Ivanovic out of Stuttgart
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In other matches, top seed Maria Sharapova suffered a shock 6-2 7-5 defeat by Hungarian veteran Greta Arn.
BBC: Heather Watson loses to Shuai Peng in Auckland quarters
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The match appeared to be plain sailing in the opening stages against the 30-year-old Arn, ranked 104th in the world.
BBC: Venus Williams & Kim Clijsters into US Open round two
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Arn led 4-0 and, despite losing momentum, still had a service game to take it to a decider at 5-3.
BBC: Venus Williams & Kim Clijsters into US Open round two
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Clijsters had to overcome a wobble in the second set to beat Greta Arn 6-0 7-5 and book her place in round two.
BBC: Venus Williams & Kim Clijsters into US Open round two
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The Londoner also came through qualifying at the Pan Pacific Open in Tokyo in September, before losing in the first round to Hungary's Greta Arn.
BBC: Andy Murray and Laura Robson set to play in Hopman Cup
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Paraguay's Rossana Neffa-De Los Rios was another comeback winner against German Greta Arn, amd her 0-6 7-6 7-6 won sets up a clash with sixth seed Alexandra Stevenson.
BBC: Farina Elia into quarters
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The New York Times on Tuesday printed text of a letter to his clients from Arn Tellem, one of the most powerful agents, urging Hunter's removal next month, and others will likely follow.
WSJ: Hunter fires family members from NBA players union