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Azarenka's reward is a clash with unseeded German Anna-Lena Groenefeld, who beat Australia's Alicia Molik 6-4 6-4.
CNN: STORY HIGHLIGHTS
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Fourth seed Angelique Kerber came through in three sets against Georgia's Anna Tatishvili, while her fellow German Sabine Lisicki beat Czech Lucie Safarova 6-2 6-4.
CNN: STORY HIGHLIGHTS
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In the only other first-round match on the opening day, Spain's Conchita Martinez ousted the only German player in the main draw, wild card Anna-Lena Groenefeld, 7-6 6-2.
BBC: SPORT | Tennis | Clijsters: Serena still the best